- Robert Downey Jr. as Tony Stark/Iron Man. Costume design by Rebecca Gregg and Laura Jean Shannon (Iron Man), Mary Zophres (Iron Man 2), Alexandra Byrne (The Avengers, Avengers: Age of Ultron), Louise Frogley (Iron Man 3, Spider-Man: Homecoming), and Judianna Makovsky (Captain America: Civil War, Avengers: Infinity War, Avengers: Endgame).
- Chris Hemsworth as Thor Odinson. Costume design by Alexandra Byrne (Thor, The Avengers, Avengers: Age of Ultron), Wendy Partridge (Thor: The Dark World), Mayes C. Rubeo (Thor: Ragnarok, Thor: Love and Thunder), and Judianna Makovsky (Avengers: Infinity War, Avengers: Endgame).
- Lauren Ridloff as Makkari. Costume design by Sammy Sheldon Differ (Eternals).
- Anthony Mackie as Sam Wilson/Falcon/Captain America. Costume design by Judianna Makovsky (Captain America: The Winter Soldier, Captain America: Civil War, Avengers: Infinity War, Avengers: Endgame), Sammy Sheldon Differ (Ant-Man), and Michael Crow (The Falcon and the Winter Soldier).
- Hugo Weaving and Ross Marquand as Johann Schmidt/Red Skull. Costume design by Anna B. Sheppard (Captain America: The First Avenger) and Judianna Makovsky (Avengers: Infinity War, Avengers: Endgame).
- Elizabeth Olsen as Wanda Maximoff/Scarlet Witch. Costume design by Mayes C. Rubeo (WandaVision), Alexandra Byrne (Avengers: Age of Ultron), Judianna Makovsky (Captain America: Civil War, Avengers: Infinity War, Avengers: Endgame), and Graham Churchyard (Doctor Strange in the Multiverse of Madness).
- Danai Gurira as Okoye. Costume design by Ruth E. Carter (Black Panther) and Judianna Makovsky (Avengers: Infinity War, Avengers: Endgame).
- Paul Rudd as Scott Lang/Ant-Man. Costume design by Sammy Sheldon Differ (Ant-Man), Judianna Makovsky (Captain America: Civil War, Avengers: Infinity War, Avengers: Endgame) and Louise Frogley (Ant-Man and the Wasp).
- Chris Pratt as Peter Quill/Star-Lord. Costume design by Alexandra Byrne (Guardians of the Galaxy), Judianna Makovsky (Guardians of the Galaxy Vol. 2, Avengers: Infinity War, Avengers: Endgame), and Mayes C. Rubeo (Thor: Love and Thunder).
- Simu Liu as Xu Shang-Chi. Costume design by Kym Barrett (Shang-Chi and the Legend of the Ten Rings).
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