#sulfides

Ion bombardment triggers a reliable quantum switch in tantalum disulfide crystals

When you toss a coin, you put it into a higher-energy state until it falls back down again. It can then end up in one of two possible states: heads or tails. No matter which state the coin was in before, after the toss both outcomes are equally likely. A team at TU Wien has analyzed a quantum system that also has two equivalent ground states. By supplying energy through ion bombardment, this state can be changed. Remarkably, however, the system behaves very differently from a coin toss: it switches every single time. After ion impact, it reliably ends up in the opposite state. For the experiment, the ion-beam equipment of TU Wien was transported to DESY in Hamburg. The crystals studied were provided by Kiel University (CAU), which also participated in the experiments at DESY. The research is published in the journal Nano Letters.

Sphalerite, Chalcopyrite, and Quartz with minor Pyrite

Rhodochrosite rhombs with purple Fluorite, Quartz, and Sulfides

Table salt enables new metallic nanotubes with potential for faster electronics

For the first time, researchers have made niobium sulfide metallic nanotubes with stable, predictable properties, a long-sought goal in advanced materials science. According to the international team, including a researcher at Penn State, that made the accomplishment, the new nanomaterial that could open the door to faster electronics, efficient electricity transport via superconductor wires and even future quantum computers was made possible with a surprising ingredient: table salt. They published their research in ACS Nano. Nanotubes are structures so small that thousands of them could fit across the width of a human hair. The tiny hollow cylinders are made by rolling up sheets of atoms; nanotubes have an unusual size and shape that can cause them to behave very differently from 3D, or bulk, materials. They can be stronger than steel but lighter than plastic, carry electricity with little resistance, conduct heat efficiently and even display exotic quantum effects.

Spinel-type sulfide semiconductors achieve room-temperature light emission across violet to orange spectrum

A spinel-type sulfide semiconductor that can emit light from violet to orange at room temperature has been developed by researchers at Science Tokyo, overcoming the efficiency limitations of current LED and solar cell materials. The material, (Zn,Mg)Sc2S4, can be chemically tuned to switch between n-type and p-type conduction, leading to future pn homojunction devices. This versatile semiconductor offers a practical path toward the development of more efficient LEDs and solar cells. LEDs, solar cells, and semiconductor lasers rely on pn junctions for their operation, where an electron-rich n-type region meets a hole-rich p-type region. At this junction, electrons and holes either recombine to produce light, as in LEDs, or are separated to generate current, as in solar cells. The efficiency of these processes depends on the material itself. Gallium arsenide (GaAs) recombines carriers efficiently and emits light, making it ideal for LEDs, while silicon excels at capturing sunlight and generating current but is a poor light emitter.