A research team from the University of Chemistry and Technology, Prague (UCT Prague) and the Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences (IOCB Prague) has created and described a new type of photoswitch. The molecule, a thienyl-based acylhydrazone, undergoes an unprecedented “closed-to-open-shell” transformation, where light converts it into a stable…

Enhanced ambient ammonia photosynthesis using nanosheets with light-switchable oxygen vacancies

Researchers have presented a strategy by simultaneously introducing light-switchable oxygen vacancy and doping mo into Bi5O7Br nanosheets for efficient photocatalytic N2 fixation. The modified photocatalyst has achieved elevated N2 fixation photoactivities by virtue of the optimized conduction band position, enhanced light availability, improved N2 adsorption and charge carrier separation.…