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Inspo:

in age order:

alex confirmed occtis was 20 on his fireside chat, and then said it several times in the campaign

the chronicles of exandria art book states keyleth left home at 20, when we meet her in the campaign it's been 2 years since then

taliesin mentioned percy being early-mid 20s in a vox machina q&a, matt also mentioned during the campaign that percy was underage when the briarwoods took over, 5 years before the campaign starts, so presumably 17 at the oldest. i think if he was younger than that then 21 is a bit young for early-mid 20s (and yeah whitestone could have an age of majority higher than 18, but again, limited range to qualify)

beau in the campaign says she's both 24 and 26 at points, but marisha on talks confirmed she lies that she's older than she is, 22-23 is more accurate

the mighty nein origins comics give two different ages for jester, one where she's 18, one where she's 28, so nothing confirmed, i picked around 24 because that feels about accurate to me

sam said veth was 25 (and did the whole small town get married right out of high school thing) on talks machina

vax says in the campaign he's 27, vex is only a few minutes younger than him and therefore also 27

azune is mentioned in c4 as having been 15 12 years ago

dorian says it in the campaign

tary calls himself "a young 28!" when vax asks how old he is

wiki says ashton's is calculable based on when his home village was destroyed

imogen says it multiple times in the campaign

sam says wick is roughly 28-29 a few times in the campaign

julien has the famously argued over "about to crest into his 30s", and the various ages people think that means. additionally aranessa who is 44 (listed in ep 26) brennan called "about 15 years older than [julien]", so yeah, 29-30

travis listed fjord as being about 30 in one talks machina, then "early 30s" in two other talks machinas

caleb says 33 in the campaign, this also tracks with the timeline of him being 16-17 when he killed his parents, 11 years in the sanatorium, 5 years on the run by the time we meet him

liam mentioned orym's age when he first saw vax on 4 sided dive, we know when that was, can calculate he's around 36-37 from that

ashley used to say a lot of different ages for pike early on in the stream/before the stream, but settled on early 40s by the end of it (which is about a year and a half to two years after the stream begins, so, 40-ish)

kattigan my estimate is based on brennan's descriptions of roughly how old he was each time we see him in a flashback

murray my estimate is based on the flashback from 25 years ago of the penteveral being founded. we can presume she was an adult (so at least 43), and we know her upper age is that she's younger than bolaire (says it in ep 4), but she feels like a young adult to me in that flashback, so i'd guess early 20s (and then +25 years for her current age)

thaisha and hal are 48, they were 19 in the flashback 29 years ago

laudna mentions being 50 at one point, but also mentions being 20 33 years ago, so somewhere in there

bertrand bell i wanna say travis mentioned his age during search for grog? but wiki doesn't list a source so can't confirm

tyranny being six months is mentioned a couple times in the campaign

molly being 2 is mentioned both in campaign and out

sam at the end of the campaign listed scanlan's age as almost 71, and then had to prompt people to get the joke of what age scanlan was at the start of the campaign a little under two years ago (he also confirms in talks machina, yeah, 69 is the entire bit)

bolaire tells us he was created a few days before rauwyn died, which we're also told in the campaign was 73 years ago

taliesin mentioned caduceus was anywhere from 80-120 on talks machina, i took the middle value and added an ish

fearne's age is listed in exu

chetney being a little over 400 is mentioned multiple times in the campaign

fresh cut grass is older than the divergence, which was over 800 years ago, though some have also noted on this post (since i haven't watched c3), that as far as his consciousness goes, he's also in the babies section!