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Formation of CL3 compound to CL2 using P2O5 (we dehydrate it, removing an OH- and H+ (H2O) from the Oxime)
The oxime is created by reacting an Aldehyde with an NH2X compound (amine) in the presence of H+
Aldehyde -> Oxime -> Nitrile
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Wolff-Kishner Reaction
Removes the carbonyl functional group.
Hydrazone comes from Carbonyl rection with NH2X
Creation of an Imine from a Carbonyl
A reversible process also driven by the removal of H2O
All NH2X react like this
Acetal Formation, driven by the removal of H2O
the entire process is reversible. It is a great way to protect ketones/aldehydes (carbonyls) from being attacked
It favors the Aldehyde. (Most likely due to steric reasons)
Acetal Formation
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Cr6+ (PCC With Acid Water Catalyst)
forms Carboxylic Acid from alcohols
H+ and water take an Aldehyde to a diol. (Gem DIN)
Reversible Addition of Water. H2O is added across the C=O bond and forms a (gem) diol
Acid Catalyzed Addition of a Carbonyl
The H+ on O makes C a better electrophile.
Ketones with acid and water form Gem Diols.
S Ylide Reaction
Sulfur is oxyphilic, but not as much as P
