A lawful evil villain methodically takes what he wants within the limits of his code of conduct without regard for whom it hurts. He cares about tradition, loyalty, and order but not about freedom, dignity, or life. He plays by the rules but without mercy or compassion. He is comfortable in a hierarchy and would like to rule, but is willing to serve. [In the case of Valentine, he served long before he decided he was better fit to rule.] He condemns others not according to their actions but according to race, religion, homeland, or social rank. He is loath to break laws or promises.
This reluctance comes partly from his nature and partly because he depends on order to protect himself from those who oppose him on moral grounds. Some lawful evil villains have particular taboos, such as not killing in cold blood (but having underlings do it) or not letting children come to harm (if it can be helped). They imagine that these compunctions put them above unprincipled villains. [ Valentine believes in pure blood Nephilim and he has those he considers worthy of existing above others. Such deaths are not part of his agenda, where as he targets other groups - namely Downworlders.]
Some lawful evil people and creatures commit themselves to evil with a zeal like that of a crusader committed to good. Beyond being willing to hurt others for their own ends, they take pleasure in spreading evil as an end unto itself. They may also see doing evil as part of a duty to an evil deity or master. [Unfortunately, Valentine whole heartedly believes in his vision and he is dedicated to it because he believes in it and what his actions stand for. He doesn't have a master or deity - he is held accountable to himself and his ideals.]
Lawful evil is sometimes called "diabolical," because devils are the epitome of lawful evil.
Lawful evil creatures consider their alignment to be the best because it combines honor with a dedicated self-interest.
Lawful evil is the most dangerous alignment because it represents methodical, intentional, and frequently successful evil.
Here are some possible adjectives describing lawful evil characters: cruel, vengeful, proud, callous, hostile, taciturn, malevolent, calculating, plotting, merciless, domineering, severe, tyrannical, commanding, organized, and respectful of authority and power.
Well known lawful evil characters from film or literature include: Darth Vader (Star Wars), Magneto (Marvel Comics), Dolores Umbridge (Harry Potter), and the Borg (Star Trek, the Next Generation).
credit and further reading can be found at the source, here!
notes in regard to valentine go to myself, at the mundanes institute
