A breakthrough manganese complex brings cheap, sustainable, and highly efficient photochemistry within reach.
Most chemical reactions rely on heat to move forward, but light has recently become an important alternative. Using light makes it possible to guide reactions with extremely fine control, a field known as photochemistry. Until now, many of these light-driven processes depended on ruthenium, osmium, or iridium -- elements that are costly, scarce, and create environmental concerns when mined.
Researchers at Johannes Gutenberg University Mainz (JGU) have now created a new metal complex built from manganese, a widely available and inexpensive element. "This metal complex sets a new standard in photochemistry: it combines a record-breaking excited-state lifetime with simple synthesis," explained Professor Katja Heinze of the JGU Department of Chemistry. "It thus offers a powerful and sustainable alternative to the noble metal complexes that have long dominated light-driven chemistry." The study recently appeared in Nature Communications.