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The strategies used by Pyne's group in the synthesis of these alkaloids can be summarised into three key steps:
reaction of a primary amine with an epoxide
the formation of a cycloalkene
the oxidation of the alkene group to form a vicinal diol.
"Chemistry" 2e - Blackman, A., Bottle, S., Schmid, S., Mocerino, M., Wille, U.
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The addition of bromine and chlorine to a cycloalkane gives a trans-dihalocycloalkane. For example, the addition of bromine to cyclohexene gives trans-1,2-dibromocyclohexane; the cis isomer is not formed.
Addition of bromine to a cycloalkene is highly stereospecific; the halogen atoms always add trans to each other.
"Chemistry" 2e - Blackman, A., Bottle, S., Schmid, S., Mocerino, M., Wille, U.
Access Full Report : https://www.predictoreports.com/reports_details?Asia-Pacific-Cyclohexene-(CAS-110-83-8)-Market-Analysis-2012-2017...
Cyclohexene is a hydrocarbon with the formula C6H10. This cycloalkene is a colorless liquid with a sharp smell. It is an intermediate in various industrial processes. Cyclohexene is not very stable upon long term storage with exposure to light and air because it forms peroxides. The Asia-Pacific Cyclohexene (CAS 110-83-8) market will reach xxx Million USD in 2018 and CAGR xx% 2018-2023. The report begins from overview of Industry Chain structure, and describes industry environment, then analyses market size and forecast of Cyclohexene (CAS 110-83-8) by product, region and application, in addition, this report introduces market competition situation among the vendors and company profile, besides, market price analysis and value chain features are covered in this report.
